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Most "remote not working" problems are actually pairing problems, so here's everything in order.
To add an additional remote: go to Settings → Controllers & Bluetooth Devices → Amazon Fire TV Remotes → Add New Remote, then hold Home for 10 seconds on the new remote.
Program the remote to control your TV (power and volume): The Alexa Voice Remote can control your TV's power, volume, and mute.
If nothing works: the remote may have failed. A replacement Fire TV remote is inexpensive, and the phone app works in the meantime.
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